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21-53-53012

RFBR-NSFC

Completed
Period: 2021–2023

RFBR-NSFC Project №21-53-53012

(2021-2023)

A project, jointly led by Prof. V. V. Kondratiev and Prof. Dr. Lijun Fu of Nanjing Tech University, and co-led by Prof. Yuping Wu, is aimed at studying new electrode materials and their electrochemical properties in zinc-ion batteries. Activities within the project will include development of methods for synthesis of new composite organic-inorganic rechargeable materials for zinc-ion batteries: both metal oxide-based cathode materials and anode materials with the production of 3D zinc electrodes. Work will be done to study the structural-chemical and functional electrochemical properties of the obtained materials: both as individual electrodes and as part of battery test cells, in traditional and new concentrated electrolytes.

The novelty of the project lies within the synthesis of composite materials with improved chemical composition based on transition metal oxides (presumably manganese oxides and vanadium oxides) with incorporation of an electro-ion-conducting component - the conducting polymer poly-3,4-ethylenedioxythiophene (PEDOT), including combinations with other ion-conducting polymers, as well as surface modification of active material grains by a shell of chemically stable conducting polymer, or creation of complex materials in the synthesis process. As one of the paths to achieve higher functional characteristics of zinc-ion batteries, the use of new compositions of concentrated electrolytes of the "water-in-salt" type is considered.

The idea for the project emerged during a visit to the Department of Electrochemistry in 2019 by Professor Yuping Wu, head of the Laboratory of New Materials for Energy at Nanjing Technical University, with the member of the same laboratory Dr. Lijun Fu, head of the joint project.

In news of the Institute of Chemistry - https://chem.spbu.ru/all-news/3160-uchjonye-iz-instituta-khimii-spbgu-zajmutsya-v-novom-godu-sovmestnymi-issledovaniyami-v-oblasti-elektrokhimii-s-kitajskimi-kollegami.html

Publications 8
The Effect of the Synthesis Method of the Layered Manganese Dioxide on the Properties of Cathode Materials for Aqueous Zinc-Ion Batteries
Kamenskii M.A., Popov A.Yu., Eliseeva S.N., Kondratiev V.V.
Russian Journal of Electrochemistry, 2024, Vol. 859, Issue 12, pp. 1092-1101
2024
Comparative Study of PEDOT- and PEDOT:PSS Modified δ-MnO2 Cathodes for Aqueous Zinc Batteries with Enhanced Properties
Kamenskii M.A., Volkov F.S., Eliseeva S.N., Holze R., Kondratiev V.V.
Journal of The Electrochemical Society, 2023, Vol. 170, Issue 1
2023
Vanadium Oxide–Conducting Polymers Composite Cathodes for Aqueous Zinc-Ion Batteries: Interfacial Design and Enhancement of Electrochemical Performance
Tolstopyatova E.G., Kamenskii M.A., Kondratiev V.V.
Energies, 2022, Vol. 15, Issue 23
2022
Vanadium Oxide-Poly(3,4-ethylenedioxythiophene) Nanocomposite as High-Performance Cathode for Aqueous Zn-Ion Batteries: The Structural and Electrochemical Characterization
Volkov F.S., Eliseeva S.N., Kamenskii M.A., Volkov A.I., Tolstopjatova E.G., Glumov O.V., Fu L., Kondratiev V.V.
Nanomaterials, 2022, Vol. 12, Issue 21
2022
Electrochemical Performance of LiMn2O4 Cathodes in Zn-Containing Aqueous Electrolytes
Kamenskii M.A., Eliseeva S.N., Volkov A.I., Kondratiev V.V.
Journal of Electrochemical Science and Technology, 2022, Vol. 13, Issue 2
2022
Electrospun V2O5 nanofibers as high-capacity cathode materials for zinc-ion batteries
Volkov A.I., Sharlaev A.S., Berezina O.Ya., Tolstopjatova E.G., Fu L., Kondratiev V.V.
Materials Letters, 2021
2021
Vanadium(V) oxide coated by poly(3,4-ethylenedioxythiophene) as cathode for aqueous zinc-ion batteries with improved electrochemical performance
Volkov F.S., Tolstopjatova E.G., Eliseeva S.N., Kamenskii M.A., Vypritskaia A.I., Volkov A.I., Kondratiev V.V.
Materials Letters, 2021
2021
EQCM study of intercalation processes into electrodeposited MnO2 electrode in aqueous zinc-ion battery electrolyte
Efremova A.O., Volkov A.I., Tolstopjatova E.G., Kondratiev V.V.
Journal of Alloys and Compounds, 2021, Vol. 892
2021
Showing - publications
Project Leader
Veniamin Kondratiev

Project Leader

Doctor of Chemical Sciences, Senior Researcher, Professor

Project Information
Duration
Status
Completed
Funding Agency
RFBR-NSFC